This could be just about anything. Apparently, when you drained and left it, there were solids left hanging onto the surface of the shell. By the time you returned, they dried and hardened.
What I would do is simply let it be, and hopefully with enough time and use, the residue will go away. Wouldn't hurt to have a rag handy when you're using it so you can help it along. Just don't use anything abrasive like a 3M 'green weenie'. (You know, one of those scratch pads used to clean tough stains on dishes and such).
But next time you drain it like this, it'll be a good idea to wash and wipe down the shell immediately after draining it - or even wipe it down before you drain, then rinse it out with a hose.
No magic answer here.
